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Geometry index : ウィキペディア英語版
Geometry index

In structural chemistry and crystallography, the geometry index or structural parameter () is the number in a range 0...1 that indicates what the geometry of the coordination center is. The first such parameter for 5-coordinate compounds was developed in 1984. Later, parameters for 4-coordinate compounds were developed.
==5-coordinate compounds==


To distinguish whether the geometry of the coordination center is trigonal bipyramidal or square pyramidal, the (originally just ) parameter was proposed by Addison ''et al.'':
:\tau_5 = \frac \approx -0.01667\alpha + 0.01667\beta
where: are the two greatest valence angles of the coordination center.
When is close to 0 the geometry is similar to square pyramidal, while if is close to 1 the geometry is similar to trigonal bipyramidal:
|File:Trigonal-bipyramidal-3D-balls.png
|alt2=Trigonal bipyramidal geometry
|Trigonal bipyramidal geometry

}}

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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